Biosorption of copper(II) onto spent biomass of Gelidiella acerosa (brown marine algae): optimization and kinetic studies

Abstract

Abstract This study exclusively focused on the potential application of an inexpensive and sustainable waste macro-algal biomass as an adsorbent for biosorption of copper ions from aqueous medium. After extraction of agar from brown macro-marine algae Gelidiella acerosa, the residual biomass without any further treatment was used as an adsorbent for the expulsion of copper from wastewater. Physicochemical parameters of biosorption like initial pH, initial concentration of Cu(II) solution and biosorbent dosage were optimized using response surface methodology. The maximum copper biosorption potential of 96.36% was observed at optimum conditions of pH of 5.31, initial concentration of 23.87 mg/l and biosorbent dosage of 0.41 g/l. Adopting FTIR and SEM techniques, the surface morphological features of biosorbent were studied. The pseudo-second-order kinetic model was found to be a proper approach to describe biosorption kinetics. All these results confirmed that spent G. acerosa could be considered as an efficient, eco-friendly and economic alternative for Cu(II) removal from aqueous solution.

Keywords

• Biosorption
• Copper
• Gelidiella acerosa
• Kinetics
• Optimization