One-Step Gas–Solid-Phase Diffusion-Induced Elemental Reaction for Bandgap-Tunable CuaAgm1Bim2In/CuI Thin Film Solar Cells

Erchuang Fan; Manying Liu; Kangni Yang; Siyu Jiang; Bingxin Li; Dandan Zhao; Yanru Guo; Yange Zhang; Peng Zhang; Chuantian Zuo; Liming Ding; Zhi Zheng

doi:10.1007/s40820-023-01033-5

Nano-Micro Letters (Mar 2023)

One-Step Gas–Solid-Phase Diffusion-Induced Elemental Reaction for Bandgap-Tunable CuaAgm1Bim2In/CuI Thin Film Solar Cells

Erchuang Fan,
Manying Liu,
Kangni Yang,
Siyu Jiang,
Bingxin Li,
Dandan Zhao,
Yanru Guo,
Yange Zhang,
Peng Zhang,
Chuantian Zuo,
Liming Ding,
Zhi Zheng

Affiliations

Erchuang Fan: Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, College of Chemical and Materials Engineering, Institute of Surface Micro and Nano Materials, Xuchang University
Manying Liu: Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, College of Chemical and Materials Engineering, Institute of Surface Micro and Nano Materials, Xuchang University
Kangni Yang: Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, College of Chemical and Materials Engineering, Institute of Surface Micro and Nano Materials, Xuchang University
Siyu Jiang: Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, College of Chemical and Materials Engineering, Institute of Surface Micro and Nano Materials, Xuchang University
Bingxin Li: Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, College of Chemical and Materials Engineering, Institute of Surface Micro and Nano Materials, Xuchang University
Dandan Zhao: Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, College of Chemical and Materials Engineering, Institute of Surface Micro and Nano Materials, Xuchang University
Yanru Guo: Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, College of Chemical and Materials Engineering, Institute of Surface Micro and Nano Materials, Xuchang University
Yange Zhang: Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, College of Chemical and Materials Engineering, Institute of Surface Micro and Nano Materials, Xuchang University
Peng Zhang: School of Materials Science and Engineering, Zhengzhou University
Chuantian Zuo: Center for Excellence in Nanoscience (CAS), Key Laboratory of Nanosystem and Hierarchical Fabrication (CAS), National Center for Nanoscience and Technology
Liming Ding: Center for Excellence in Nanoscience (CAS), Key Laboratory of Nanosystem and Hierarchical Fabrication (CAS), National Center for Nanoscience and Technology
Zhi Zheng: Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, College of Chemical and Materials Engineering, Institute of Surface Micro and Nano Materials, Xuchang University

DOI: https://doi.org/10.1007/s40820-023-01033-5
Journal volume & issue: Vol. 15, no. 1
pp. 1 – 11

Abstract

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Highlights The CuaAgm1Bim2In/CuI bilayer films are prepared simultaneously in situ by a one-step low-temperature gas-solid phase diffusion induced elemental reaction without spin coating. A new type of CuaAgm1Bim2In photovoltaic material was originally designed to reduce the bandgap of this class of materials from 2.06 to 1.78 eV by breaking the restriction of double perovskite structure with a ratio of Ag:Bi = 1:1. The power conversion efficiency (PCE) of solar cell with a structure of FTO/TiO2/CuaAgm1Bim2In/CuI/carbon reached 2.76%, which is the highest PCE for CuaAgm1Bim2In absorbers.

Published in Nano-Micro Letters

ISSN: 2311-6706 (Print); 2150-5551 (Online)
Publisher: SpringerOpen
Country of publisher: Germany
LCC subjects: Technology
Website: http://www.springer.com/40820

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