Trinuclear Mixed-valent Manganese Complex with Non-schiff-base Tetradentate Ligand Showing a Ferromagnetic Coupling

Masahiro Mikuriya; Iyo Matsushima; Daisuke Yoshioka

doi:10.19261/cjm.2017.446

Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry (Dec 2017)

Trinuclear Mixed-valent Manganese Complex with Non-schiff-base Tetradentate Ligand Showing a Ferromagnetic Coupling

Masahiro Mikuriya,
Iyo Matsushima,
Daisuke Yoshioka

Affiliations

Masahiro Mikuriya: Department of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, Japan
Iyo Matsushima: Department of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, Japan
Daisuke Yoshioka: Department of Applied Chemistry for Environment and Research Center for Coordination Molecule-based Devices, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda 669-1337, Japan

DOI: https://doi.org/10.19261/cjm.2017.446
Journal volume & issue: Vol. 12, no. 2
pp. 34 – 40

Abstract

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Mixed-valent trinuclear manganese complex with N,N’-bis(2-hydroxy-3,5-dimethylbenzyl-N,N’-dimethyl-1,2-ethanediamine (H2hdde), [Mn3(hdde)2(CH3CO2)2(CH3O)2], was synthesized. The X-ray crystal structure analysis revealed a linearly arrangement of MnIII-MnII-MnIIIcore, where a ferromagnetic coupling (J = 2.62 cm–1) between the MnIII and MnII ions.

Published in Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry

ISSN: 1857-1727 (Print); 2345-1688 (Online)
Publisher: Academy of Sciences of Moldova, Institute of Chemistry
Country of publisher: Moldova, Republic of
LCC subjects: Science: Chemistry: General. Including alchemy
Website: http://www.cjm.asm.md/

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