High-Efficiency Selective Adsorption of Rubidium and Cesium from Simulated Brine Using a Magnesium Ammonium Phosphate Adsorbent
Haining Liu,
Yanping Wang,
Qiongyuan Zhang,
Wenjie Han,
Huifang Zhang,
Xiushen Ye
Affiliations
Haining Liu
Key Laboratory of Green and High-End Utilization of Salt Lake Resources, Key Laboratory of Salt Lake Resources Chemistry of Qinghai Province, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China
Yanping Wang
Key Laboratory of Green and High-End Utilization of Salt Lake Resources, Key Laboratory of Salt Lake Resources Chemistry of Qinghai Province, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China
Qiongyuan Zhang
Key Laboratory of Green and High-End Utilization of Salt Lake Resources, Key Laboratory of Salt Lake Resources Chemistry of Qinghai Province, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China
Wenjie Han
Key Laboratory of Green and High-End Utilization of Salt Lake Resources, Key Laboratory of Salt Lake Resources Chemistry of Qinghai Province, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China
Huifang Zhang
Key Laboratory of Green and High-End Utilization of Salt Lake Resources, Key Laboratory of Salt Lake Resources Chemistry of Qinghai Province, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China
Xiushen Ye
Key Laboratory of Green and High-End Utilization of Salt Lake Resources, Key Laboratory of Salt Lake Resources Chemistry of Qinghai Province, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China
Rubidium and cesium are critical strategic elements, and their development and utilization are of great significance. In this study, a magnesium ammonium phosphate (MAP) adsorbent was prepared and characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET) surface area analysis, and Fourier transform infrared spectroscopy (FTIR). The adsorption performance of the adsorbent for Rb+ and Cs+ in solution was investigated. The results showed that the adsorbent exhibited high adsorption capacities of 2.83 mol/g for Rb+ and 4.37 mol/g for Cs+. In simulated brine, the adsorbent demonstrated excellent selectivity for Cs+. Kinetic and thermodynamic studies indicated that the adsorption process followed a pseudo-second order kinetic model and Langmuir isotherm model. The primary adsorption mechanism was an ion exchange. The development of this adsorbent holds significant promise for the extraction of rubidium and cesium from liquid resources.
