2-(4,5-Dimethoxy-2-nitrophenyl)-4-methoxy-3-methyl-9-phenylsulfonyl-9H-carbazole

P. Narayanan; K. Sethusankar; Velu Saravanan; Arasambattu K. Mohanakrishnan

doi:10.1107/S1600536814003535

Acta Crystallographica Section E (Mar 2014)

2-(4,5-Dimethoxy-2-nitrophenyl)-4-methoxy-3-methyl-9-phenylsulfonyl-9H-carbazole

P. Narayanan,
K. Sethusankar,
Velu Saravanan,
Arasambattu K. Mohanakrishnan

Affiliations

P. Narayanan: Department of Physics, RKM Vivekananda College (Autonomous), Chennai 600 004, India
K. Sethusankar: Department of Physics, RKM Vivekananda College (Autonomous), Chennai 600 004, India
Velu Saravanan: Department of Organic Chemistry, University of Madras, Maraimalai campus, Chennai 600 025, India
Arasambattu K. Mohanakrishnan: Department of Organic Chemistry, University of Madras, Maraimalai campus, Chennai 600 025, India

DOI: https://doi.org/10.1107/S1600536814003535
Journal volume & issue: Vol. 70, no. 3
pp. o336 – o337

Abstract

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In the title compound, C28H24N2O7S, the carbazole system is essentially planar, with a maximum deviation of 0.0644 (19) Å for the C atom connected to the 4,5-dimethoxy-2-nitrophenyl group. The dihedral angle between the carbazole moiety and the dimethoxy-substituted nitrophenyl ring is 58.55 (7)°. The sulfonyl group forms two intramolecular C—H...O bonds with the adjacent carbazole system, forming two cyclic S(6) motifs. In the crystal, molecules are linked along the a axis in bands consisting of cyclic R33(15) motifs through two further C—H...O hydrogen bonds.

Published in Acta Crystallographica Section E

ISSN: 1600-5368 (Online)
Publisher: International Union of Crystallography
Country of publisher: United Kingdom
LCC subjects: Science: Chemistry: Crystallography
Website: https://journals.iucr.org/e/

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