Isotopic Transient Kinetic Analysis of Soot Oxidation on Mn₃O₄, Mn₃O₄-CeO₂, and CeO₂ Catalysts in Tight Contact Conditions

Abstract

The reaction mechanism of soot oxidation on Mn (Mn3O4), Mn-Ce (Mn3O4-CeO2), and Ce (CeO2) catalysts in tight contact conditions was investigated using ITKA (isotopic transient kinetic analysis). The obtained results suggest that lattice-bulk oxygen from all studied catalysts takes part in the soot oxidation process but with varying relative contributions: for the Ce catalyst, this contribution is practically 100%, whereas with decreasing Ce content in Mn-Ce catalysts, the significance of lattice-bulk oxygen for soot oxidation diminishes. For the Mn catalyst, it is estimated to be below 50%. Moreover, strong interactions between Mn and Ce ions were observed, increasing oxygen mobility in the catalyst crystal lattice and affecting the activity of Mn-Ce catalysts.

Keywords

• diesel soot oxidation
• CeO₂
• Mn₃O₄
• Mn₃O₄-CeO₂
• ITKA