Operation parameters study on the performance of PEMFC based orthogonal test method

Abstract

By selecting five key operational parameters—inlet temperature, operating temperature, anode humidity, cathode humidity, and operating pressure—and using PEMFC power density, membrane temperature difference, and membrane water content as performance indicators, simulations were conducted using 3D CFD modeling and orthogonal experiments to identify the most significant factors influencing PEMFC performance and determine the optimal operational parameter combination. The results show that working pressure has the most significant impact on PEMFC performance. Pressure variations cause significant changes in diffusion and heat conduction within the PEMFC. When the working pressure increases from 1.0 MPa to 3.0 MPa, the power density increases by approximately 11.2 %, but the temperature difference within the membrane increases by about 30.5 %. The difference between operating temperature and inlet temperature directly leads to changes in the temperature difference within the membrane. Moreover, changes in operating temperature greatly affect the water content within the proton exchange membrane, which in turn impacts the PEMFC's power density. When the operating temperature increases from 60 °C to 100 °C, the water content within the membrane decreases by approximately 50.5 %, and the power density decreases by 60.4 %. By optimizing the combination of operating parameters using a comprehensive scoring method, the temperature difference within the membrane can be controlled at 27.78 °C while ensuring the power density is increased to 0.92 W/cm2.

Keywords

• PEMFC
• Operational parameters study
• Orthogonal experimental
• Optimization