Acta Crystallographica Section E (Jan 2009)

[Benzyl(2-pyridylmethyl)amine]dichloridomercury(II)

  • Hoe-Joo Seo,
  • Young-Inn Kim,
  • You-Soon Lee,
  • Sung Kwon Kang

DOI
https://doi.org/10.1107/S1600536808040695
Journal volume & issue
Vol. 65, no. 1
pp. m55 – m55

Abstract

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The Hg atom in the title compound, [HgCl2(C13H14N2)], adopts a distorted tetrahedral geometry, being ligated by two N atoms of the benzyl(2-pyridylmethyl)amine (bpma) ligand and two Cl atoms. The dihedral angle between the least-squares planes through the chelate ring and Cl—Hg—Cl atoms is 85.4 (1)°. The phenyl ring on the bpma ligand is twisted out of the pyridine plane, forming a dihedral angle of 76.0 (3)°. Disorder in this ring is also noted with two coplanar conformations having equal site occupancies.