Acta Crystallographica Section E: Crystallographic Communications (Feb 2016)

Crystal structure of (2Z,5Z)-3-(4-methoxyphenyl)-2-[(4-methoxyphenyl)imino]-5-[(E)-3-(2-nitrophenyl)allylidene]-1,3-thiazolidin-4-one

  • Rachida Rahmani,
  • Ahmed Djafri,
  • Jean-Claude Daran,
  • Ayada Djafri,
  • Abdelkader Chouaih,
  • Fodil Hamzaoui

DOI
https://doi.org/10.1107/S2056989016000207
Journal volume & issue
Vol. 72, no. 2
pp. 155 – 157

Abstract

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In the title compound, C26H21N3O5S, the thiazole ring is nearly planar with a maximum deviation of 0.017 (2) Å, and is twisted with respect to the three benzene rings, making dihedral angles of 25.52 (12), 85.77 (12) and 81.85 (13)°. In the crystal, weak C—H...O hydrogen bonds and C—H...π interactions link the molecules into a three-dimensional supramolecular architecture. Aromatic π–π stacking is also observed between the parallel nitrobenzene rings of neighbouring molecules, the centroid-to-centroid distance being 3.5872 (15) Å.

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