Polymers (Jun 2024)

Investigation of Recycled Expanded Polyamide Beads through Artificial Ageing and Mechanical Recycling as a Proof of Concept for Circular Economy

  • Sören Handtke,
  • Lena Brömstrup,
  • Jörg Hain,
  • Fabian Fischer,
  • Tim Ossowski,
  • Sven Hartwig,
  • Klaus Dröder

DOI
https://doi.org/10.3390/polym16121730
Journal volume & issue
Vol. 16, no. 12
p. 1730

Abstract

Read online

Car manufacturers are currently challenged with increasing the sustainability of their products and production to comply with sustainability requirements and legislation. One way to enhance product sustainability is by reducing the carbon footprint of fossil-based plastic parts. Particle foams are a promising solution to achieve the goal of using lightweight parts with minimal material input. Ongoing developments involve the use of expanded particle foam beads made from engineering plastics such as polyamide (EPA). To achieve this, a simulated life cycle was carried out on virgin EPA, including mechanical recycling. The virgin material was processed into specimens using a steam-free method. One series was artificially aged to replicate automotive life cycle stresses, while the other series was not. The mechanical recycling and re-foaming of the minipellets were then carried out, resulting in an EPA particle foam with 100% recycled content. Finally, the thermal and chemical material properties were comparatively analysed. The study shows that the recycled EPA beads underwent polymer degradation during the simulated life cycle, as evidenced by their material properties. For instance, the recycled beads showed a more heterogeneous molecular weight distribution (an increase in PDI from two to three), contained carbonyl groups, and exhibited an increase in the degree of crystallization from approximately 24% to 36%.

Keywords