Química Nova (Jan 2012)

Desenvolvimento de um algoritmo para identificação e correção de spikes em espectroscopia Raman de imagem

  • Guilherme Post Sabin,
  • André Marcelo de Souza,
  • Márcia Cristina Breitkreitz,
  • Ronei Jesus Poppi

DOI
https://doi.org/10.1590/S0100-40422012000300030
Journal volume & issue
Vol. 35, no. 3
pp. 612 – 615

Abstract

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Raman imaging spectroscopy is a highly useful analytical tool that provides spatial and spectral information on a sample. However, CCD detectors used in dispersive instruments present the drawback of being sensitive to cosmic rays, giving rise to spikes in Raman spectra. Spikes influence variance structures and must be removed prior to the use of multivariate techniques. A new algorithm for correction of spikes in Raman imaging was developed using an approach based on comparison of nearest neighbor pixels. The algorithm showed characteristics including simplicity, rapidity, selectivity and high quality in spike removal from hyperspectral images.

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