Nature Communications (Feb 2016)

A four-coordinate cobalt(II) single-ion magnet with coercivity and a very high energy barrier

  • Yvonne Rechkemmer,
  • Frauke D. Breitgoff,
  • Margarethe van der Meer,
  • Mihail Atanasov,
  • Michael Hakl,
  • Milan Orlita,
  • Petr Neugebauer,
  • Frank Neese,
  • Biprajit Sarkar,
  • Joris van Slageren

DOI
https://doi.org/10.1038/ncomms10467
Journal volume & issue
Vol. 7, no. 1
pp. 1 – 8

Abstract

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Bistable single-molecule magnets potentially allow information storage at extremely high densities. Here, the authors study an air- and moisture-stable mononuclear tetrahedral cobalt(II) complex, elucidating the origin of its pronounced magnetic bistability.