Effects of Modified Cellulose Fiber and Nanofibril Integration on Basic and Thermo-Mechanical Properties of Paper

Abstract

This study investigates the influence of fiber modification methods and beating degrees on the properties of paper sheets. Two different methods were used to modify fibers: NaOH + urea and TEMPO ((2,2,6,6-tetramethylpiperidin-1-yl)oxidanyl) and blended with traditional paper fibers. Subsequently, we evaluated the resulting sheets for their optical, strength, and thermo-mechanical characteristics. Notably, we also scrutinized sheets created exclusively with 100% TEMPO-modified fibers. The addition of modified fibers led to improvements in several strength properties, but it had a noteworthy negative impact on the optical properties of TEMPO-treated fibers compared to the other papers. Furthermore, thermal analysis revealed that the contraction rates of the samples increased considerably up to 40–50 °C for the out-of-plane direction and surpassed 130 °C for the in-plane direction. In general, the inclusion of modified fibers had a significant effect on thermo-mechanical properties. Specifically, TEMPO modification resulted in an increase in the maximum in-plane contraction ratio, shifting it from −0.40% to −0.59%, along with its corresponding temperature. This research underscores the potential of modified fibers to enhance paper properties and contribute to the development of more sustainable paper-based products.

Keywords

• modified fibers
• nanocellulose
• TEMPO
• mechanical properties
• optical properties
• thermal contraction