Acta Crystallographica Section E (Oct 2008)

1-Bromoacetyl-2,6-bis(4-methoxyphenyl)-3,5-dimethylpiperidin-4-one

  • Y. T. Jeong,
  • S. Kabilan,
  • D. Velmurugan,
  • G. Aridoss,
  • R. Ramachandran

DOI
https://doi.org/10.1107/S1600536808030213
Journal volume & issue
Vol. 64, no. 10
pp. o2009 – o2010

Abstract

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In the title compound, C23H26BrNO4, the piperidinone ring adopts a boat conformation. The dihedral angle between the two benzene rings is 70.9 (1)°. The two methoxy groups are close to coplanar with the attached benzene rings [C—C—O—C torsion angles of 6.3 (5) and 16.4 (4)°]. A weak C—H...Br intramolecular interaction is observed. In the crystal structure, molecules are linked into a chain along [101] by intermolecular C—H...O hydrogen bonds. A short intermolecular Br...O contact [3.063 (2) Å] is observed.