AIP Advances (May 2018)

Tailoring magnetic properties of self-biased hexaferrites using an alternative copolymer of isobutylene and maleic anhydride

  • Chuanjian Wu,
  • Zhong Yu,
  • Alexander S. Sokolov,
  • Chengju Yu,
  • Ke Sun,
  • Xiaona Jiang,
  • Zhongwen Lan,
  • Vincent G. Harris

DOI
https://doi.org/10.1063/1.5007709
Journal volume & issue
Vol. 8, no. 5
pp. 056221 – 056221-6

Abstract

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Discussed is a novel self-biased hexaferrite gelling system based on a nontoxic and water-soluble copolymer of isobutylene and maleic anhydride. This copolymer simultaneously acts as a dispersant and gelling agent, and recently received much attention from the ceramics community. Herein its effects on the rheological conditions throughout magnetic-field pressing, and consequently, orientation, density and magnetic properties of textured hexaferrites were investigated. Ka-band FMR linewidths were measured, and the crystalline anisotropy and porosity induced linewidth broadening were estimated according to Schlömann’s theory. The copolymer allowed to reduce the friction between micron-sized magnetic particulates, resulting in higher density and degree of crystalline orientation, and lower FMR linewidth.