IUCrJ (Nov 2018)

Self-adapted clustering of solute atoms into a confined two-dimensional prismatic platelet with an ellipse-like quasi-unit cell

  • Hongbo Xie,
  • Junyuan Bai,
  • Hucheng Pan,
  • Xueyong Pang,
  • Yuping Ren,
  • Shineng Sun,
  • Liqing Wang,
  • Hong Zhao,
  • Boshu Liu,
  • Gaowu Qin

DOI
https://doi.org/10.1107/S205225251801415X
Journal volume & issue
Vol. 5, no. 6
pp. 823 – 829

Abstract

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This paper reports a new structured prismatic platelet, self-assembled by an ellipse-like quasi-unit cell, precipitated in Mg–In–Yb and Mg–In–Ca ternary alloys and aged isothermally at 200°C using aberration-corrected high-angle annular dark-field scanning transmission electron microscopy combined with density functional theory computations. The ordered stacking of solute atoms along the [0001]α direction based on elliptically shaped self-adapted clustering leads to the generation of the quasi-unit cell. The bonding of these ellipse-like quasi-unit-cell rods by the Mg atomic columns along the 〈11{\overline 2}0〉α directions formed a two-dimensional planar structure, which has three variants with a {10{\overline 1}0}α habit plane and full coherence with the α-Mg matrix. This finding is important for understanding the clustering and stacking behaviors of solute atoms in condensed matter, and is expected to guide the future design of novel high-strength Mg alloys strengthened by such high-density prismatic platelets.

Keywords