Extraction of Pb (II) and Co (II) using N,N-dioctylsuccinamate based room temperature ionic liquids containing aliphatic and aromatic cations

Abstract

Synthesis and Characterization of six novel N,N-dioctylsuccinamate based room temperature ionic liquids (RTILs) bearing imidazolium, pyridinium, ester imidazolium, and quaternary ammonium cations is reported. Extraction of Pb(II) and Co(II) by these RTILs has been investigated. Ionic liquids (ILs) synthesized were [C4mim][N88SA], [C8mim][N88SA], [C4Py][N88SA], [C8Py][N88SA], [α-mim-ester][N88SA] and [N2244][N88SA] termed as L1, L2, L3, L4, L5 and L6 respectively. Liquid-liquid extraction was performed and all the six systems showed excellent extractability results for both Pb(II) and Co(II). During the process of extraction several factors i.e., nature of cation, pH of the aqueous phase, equilibration time, and initial metal ion concentration were investigated. The extraction efficiency of above 98 % for all types of extractants was observed. The nature of cation its concentration, equilibration time, and pH of the aqueous phase significantly influenced the extraction efficiency. Maximum extraction was observed at pH values between 4 and 8 and optimum contact time was observed to be 40–45 min. Increasing the metal ion concentration decreased the extraction efficiency. The extraction efficiency of both metal ions decreased in the order [N88SA][C8mim] (L2) > [α-mim-Ester][N88SA] (L5) > [N88SA][C4mim] (L1). This is evident from the order of extraction behaviour that increasing the bulkiness of cation, results in stronger complexation, hence increasing extraction.

Keywords

• RTILs
• Imidazolium
• Pyridinium
• Quarternary Ammonium
• N
• N-dioctylsuccinamate