Memoirs of the Scientific Sections of the Romanian Academy (Oct 2014)
New possibilities for the synthesis of reactive functional aminopolysilanes using azide pathway
Abstract
Two new reaction frameworks with high stereospecificity and high yields are described. Azidopolysilanes offers multiple options for obtaining aminopolysilanes, either by reducing the azido group using the Staudinger technique or by Huisgen 1,3 cycloaddition reaction with ethynylaniline. The obtained aminopolysilanes were structurally characterized by 1H-NMR, FT-IR, elemental analysis. The optical properties were determined by fluorescence spectroscopy.
