Hot subduction in the southern Paleo-Asian Ocean: Insights from clinopyroxene chemistry and Sr–Nd–Hf–Pb isotopes of Carboniferous volcanics in West Junggar

Abstract

The chemical evolution and pressure–temperature conditions of subduction zone magmatism along ancient suture zones in orogenic belts can provide important information regarding plate convergence processes in paleo-oceans. Carboniferous magmatism in West Junggar is key to understanding the tectonothermal and subduction history of the Junggar Ocean, which was a branch of the Paleo-Asian Ocean, as well as the accretionary processes in the southwestern Central Asian Orogenic Belt (CAOB). We undertook a geochronological, mineralogical, geochemical, and Sr–Nd–Hf–Pb isotopic study of volcanic rocks from the Baikouquan area of West Junggar. We used these data to determine the petrogenesis, mantle source, and pressure–temperature conditions of these magmas, and further constrain the subduction and tectonic history of the Junggar Ocean. The studied volcanic rocks yielded zircon U–Pb ages of 342–337 Ma and are characterized by enrichments of large-ion lithophile elements (LILEs), and depletions in high-field-strength elements (HFSEs), indicative of an island arc affinity. The volcanic rocks have positive ƐNd(t) (5.83–7.04) and ƐHf(t) (13.47–15.74) values, 87Sr/86Sr(t) ratios of 0.704023–0.705658, and radiogenic 207Pb/204Pb(t) and 208Pb/204Pb(t) ratios at a given 206Pb/204Pb(t) ratio, indicative of a depleted mantle source contaminated by subduction-related materials. Geochemical modeling calculations indicate that ≤1% of a subduction component comprising fluid and sediment melt could have generated the source of the parental melts of the Baikouquan volcanic rocks. Clinopyroxene phenocrysts in the volcanic rocks are classified as high- and low-Ti clinopyroxene, and pressure–temperature calculations suggest the host rocks formed at high temperatures (∼1300 °C) and shallow to moderate depths (<2 GPa). The magma was probably generated by hot and hydrous melting in a mantle wedge in response to subduction of young, hot oceanic lithosphere. The present results, combined with published data, suggest that the Baikouquan volcanic rocks record a transition in tectonic setting from normal cold to anomalous hot subduction of young oceanic lithosphere close to a mid-ocean ridge. This indicates ridge subduction began shortly after 337 Ma. Our results provide new insights into the tectonomagmatic evolution during intra-oceanic subduction prior to ridge subduction.

Keywords

• Hot subduction
• Sr–Nd–Hf–Pb isotopes
• Clinopyroxene chemistry
• West Junggar
• Central Asian Orogenic Belt