Crystals
(Nov 2018)
Synthesis of Star-Shaped Boron Carbide Micro-Crystallites under High Pressure and High Temperatures
Vladimir P. Filonenko,
Pavel V. Zinin,
Igor P. Zibrov,
Alexander S. Anokhin,
Elena V. Kukueva,
Sergey G. Lyapin,
Vyacheslav Y. Fominski
Affiliations
Vladimir P. Filonenko
Institute for High Pressure Physics, Russian Academy of Sciences, 108840 Troitsk, Moscow, Russia
Pavel V. Zinin
Scientific-Technological Center of Unique Instrumentation, Russian Academy of Sciences, 117342 Moscow, Russia
Igor P. Zibrov
Institute for High Pressure Physics, Russian Academy of Sciences, 108840 Troitsk, Moscow, Russia
Alexander S. Anokhin
Institute of Metallurgy and Materials Science, Russian Academy of Sciences, 119991 Moscow, Russia
Elena V. Kukueva
National Research Center, Kurchatov Institute, 123182 Moscow, Russia
Sergey G. Lyapin
Institute for High Pressure Physics, Russian Academy of Sciences, 108840 Troitsk, Moscow, Russia
Vyacheslav Y. Fominski
Institute of Laser and Plasma Technologies, National Research Nuclear University MEPhI (Moscow Engineering Physics Institute), 115409 Moscow, Russia
DOI
https://doi.org/10.3390/cryst8120448
Journal volume & issue
Vol. 8,
no. 12
p.
448
Abstract
Read online
We synthesized star-shaped pentagonal microcrystals of boron carbide with an extremely low carbon content (~5%), from m-carborane under high pressure (7 GPa) and high temperature (1370⁻1670 K). These crystals have five-fold symmetry and grow in the shape of stars. A 5-fold symmetry in large micron-sized crystals is extremely rare making this a striking observation.
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