Polymeric ionic liquid as novel catalyst for the Prins reaction

Abstract

A series of micro-mesoporous polymeric ionic liquids (PILs) have been successfully synthesized by the method of anion and cation copolymerization. Then use FT-IR, N2 adsorption–desorption isotherms, SEM, and TG to characterize them. Furthermore, the catalytic performance of the synthesized PILs was investigated for the Prins reaction of propylene with 1, 3, 5-trioxane. Among the four PILs synthesized, VIMBs-DVB-SSA has better catalytic activities for the Prins reaction. Under the optimal conditions, 100 °C, 8 wt%, 4 h and n (propylene)/n (1, 3, 5-trioxane) = 4:1, the conversion of formaldehyde (99.8%) and selectivity (81.7%) for 4-methyl-1, 3-dioxane. In addition, the effects of reaction time, catalyst dosage, and reaction temperature and mole ratio of reaction substrates on the reaction were also investigated. The prepared catalyst had good thermal stability and can be reused easily.

Keywords

• Polymeric ionic liquids
• Prins reaction
• 4-methyl-1, 3-dioxane