Ru(III), Cr(III), Fe(III) complexes of Schiff base ligands bearing phenoxy Groups: Application as catalysts in the synthesis of vitamin K3

Abstract

Two polydentade Schiff base ligands and their Ru(III), Cr(III) and Fe(III) complexes were synthesized and characterized by elemental analysis (C, H, N), UV/Vis, FT IR, 1H and 13C NMR, LC–MS/MS, molar conductivity and magnetic susceptibility techniques. The absorption bands in the electronic spectra and magnetic moment measurements verified an octahedral environment around the metal ions in the complexes. The thermal stabilities were investigated using TGA. The synthesized complexes were used in the catalytic oxidation of 2-methyl naphthalene (2MN) to 2-methyl-1,4-naphthoquinone; vitamin K3, menadione, 2MNQ; using hydrogen peroxide, acetic acid and sulfuric acid. L1-Fe(III) complex showed very efficient catalytic activity with 58.54% selectivity in the conversions of 79.11%. Keywords: Schiff base, Ru(III), Cr(III) and Fe(III) complexes, Catalyst, Vitamin K, Menadione