Acta Crystallographica Section E (Apr 2011)

3,5-Bis(4-chlorobenzylidene)-1-methylpiperidin-4-one

  • Volodymyr V. Nesterov,
  • Sergey S. Sarkisov,
  • Vladimir Shulaev,
  • Vladimir N. Nesterov

DOI
https://doi.org/10.1107/s1600536811006994
Journal volume & issue
Vol. 67, no. 4
pp. o760 – o761

Abstract

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In the title molecule, C20H17Cl2NO, the central heterocyclic ring adopts a flattened boat conformation. The dihedral angles between the planar part of this central heterocyclic ring [maximum deviation = 0.004 (1) Å] and the two almost planar side-chain fragments [maximum deviations = 0.015 (1) and 0.019 (1) Å], that include the aromatic ring and bridging atoms, are 18.1 (1) and 18.0 (1)°. In the crystal, pairs of weak intermolecular C—H...O hydrogen bonds link molecules into inversion dimers that form stacks along the a axis. The structure is further stabilized by weak intermolecular C—H...π interactions involving the benzene rings.