Removal of phosphate with a polyacrylonitrile composite functionalized by a metal organic framework-enhanced layered double hydroxide

Abstract

Excessive phosphorus causes eutrophication problems. The adsorptive removal of phosphate is prevalent and practical in large-scale applications, such as column adsorption. A metal organic framework (MOF)-enhanced layered double hydroxide (LDH) adsorbent material was developed and studied for batch adsorption and then combined with polyacrylonitrile (PAN) to form MOF/LDH/PAN composite beads working as a functional material for columns. Scanning electron microscopy (SEM) images showed the well-dispersed adsorbent powder in porous composite beads. The Fowler–Guggenheim isotherm model described the phosphate adsorption behavior of the MOF/LDH powder with a maximum capacity of 74.96 mg P/g. Mass transfer in the composite beads was successfully described with the Fickian diffusion model. The composite-packed fixed bed treated 37.95 BVs of the influent (55.51 mg P/L phosphate solution) and achieved an uptake of 18.92 mg P/g, with a removal efficiency of 96.42%, before the breakthrough point in the column study. The phosphate-loaded composite bed was regenerated with 0.1 M NaOH to 70% efficiency within 30 BVs. The polymer composite can be considered a practical solution for adsorption-based water treatment applications in tank and column processes where powder adsorbents cannot be applied. HIGHLIGHTS Zn- and Al-based LDH were enhanced with MOF to produce a new adsorbent material for phosphate removal.; The synthesized adsorbent outperformed both precursors regarding phosphate adsorption.; The Fowler–Guggenheim isotherm suggests repulsive interactions between adsorbates.; Polyacrylonitrile-supported MOF/LDH/PAN composite beads perform well in an adsorption column.;

Keywords

• column adsorption
• layered double hydroxide
• metal organic framework
• phosphate adsorption
• polyacrylonitrile polymer composite