Crystals (Aug 2023)

Crystal Structure and Microwave Dielectric Property of <i>x</i>MgO-SiO<sub>2</sub> (<i>x</i> = 1~2) System for 5G Applications

  • Yan Wang,
  • Jiajing Li,
  • Haipeng Zhu,
  • Qilei Wang,
  • Tulai Sun,
  • Tao Ni,
  • Yanghong Lin,
  • Yu Liu,
  • Minmin Mao,
  • Ji Hu,
  • Bing Liu,
  • Hadi Barzegar Bafrooei,
  • Zhongyan Ma,
  • Yingjie Ren,
  • Feng Shi,
  • Ehsan Taheri-Nassaj,
  • Dawei Wang,
  • Kaixin Song

DOI
https://doi.org/10.3390/cryst13091296
Journal volume & issue
Vol. 13, no. 9
p. 1296

Abstract

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Mg2SiO4 and MgSiO3 ceramics with superior microwave dielectric properties are considered to be promising candidates for 5G applications. However, a slight deviation from the stoichiometric Mg/Si ratio will significantly influence their microwave dielectric properties, which will hinder their practical applications. In this work, the xMgO-SiO2 (x = 1~2) ceramics were synthesized by a solid-state reaction method. The influence of the Mg/Si ratio x on the crystalline phase, microstructure, and microwave dielectric properties was investigated through X-ray diffraction (XRD), a scanning electron microscope (SEM), and the resonant cavity method. The XRD patterns revealed the coexistence of Mg2SiO4 and MgSiO3 within the x range of 1~2, which was further demonstrated by the energy-dispersive X-ray spectra. The SEM images show a typical polycrystalline morphology of ceramics with an inhomogeneous grain size distribution. It is found that the microwave dielectric properties fluctuate at both sides of the x range while those remain relatively stable with minor changes at the intermediate components, indicating an obvious low composition dependence helpful for practical applications. Further, a demonstrator of a microstrip patch antenna for 5G applications using the 1.5MgO-SiO2 ceramic was designed and fabricated, and a return loss of −16.2 dB was demonstrated, which demonstrated the potential applications.

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