Zhejiang Daxue xuebao. Lixue ban (Sep 2012)

Removal of Ni2+ and catalytic dechlorination of chlorophenol from contaminated water by zero-valent iron(零价铁去除水中Ni2+及对有机氯脱氯的催化作用)

  • ZHANGZhen(张珍),
  • JINJian(金剑),
  • JIANGJin-hua(江锦花),
  • XUXin-hua(徐新华)

DOI
https://doi.org/10.3785/j.issn.1008-9497.2012.05.011
Journal volume & issue
Vol. 39, no. 5
pp. 547 – 551

Abstract

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为考察零价铁(Fe0)修复Ni2+污染水体的效果及同步修复Ni2+和有机氯的可能性，考察了 Fe0对水中Ni2+的去除效果及Ni2+对有机氯脱氯的催化作用.实验结果表明，Fe0除镍反应符合拟一级反应动力学特征，表观反应速率常数(kobs)随铁粉颗粒粒径的减小而增大，铁粉颗粒粒径由2. 000〜0. 425，0. 425〜0. 150，0. 150〜0. 075减小到80%)，这为Fe0修复技术的实际应用奠定了基础.

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