Electrochemical Properties of Ultrathin LiNi_1/3Mn_1/3Co_1/3O₂ (NMC111) Slurry-Cast Li-Ion Battery

Abstract

In thin LiNi1/3Mn1/3Co1/3O2 (NMC111) electrodes, pseudocapacitive behavior is notably enhanced due to their increased surface-to-volume ratio, which intensifies the role of the electrode–electrolyte interface. This behavior is driven by fast, reversible redox reactions and ion intercalation occurring near the surface, where the shorter diffusion path allows for more efficient ionic transport. The reduced thickness of the electrodes shortens the Li-ion diffusion distance, improving the diffusion coefficient by a factor of 40 compared to thicker electrodes, where ion transport is hindered by longer diffusion paths. The increased surface area and shorter diffusion paths promote faster electrochemical kinetics, allowing for quicker ion intercalation and deintercalation processes. The thin-film configuration enhances pseudocapacitive charge storage, which is essential for applications requiring rapid charge and discharge cycles. As a result, the combination of improved Li-ion diffusion and enhanced surface activity contributes to superior electrochemical performance, offering higher power densities, faster energy delivery, and better rate capability. This improvement in performance makes thin NMC111 electrodes particularly advantageous for applications such as high-power energy storage systems, where fast kinetics and high power densities are critical. These findings highlight the importance of interface engineering and material morphology in optimizing the performance of Li-ion batteries and similar electrochemical energy storage devices.

Keywords

• Li-ion diffusivity
• charge storage mechanism
• NMC111
• pseudocapacitance