Two-dimensional structure of poly[[[μ2-1,4-bis(pyridin-4-yl)butane]bis(μ4-pentanedioato)dicopper(II)] acetonitrile disolvate]

Abstract

In the title compound, {[Cu2(μ4-C5H6O4)2(μ2-C14H16N2)]·2CH3CN}n, the Cu2 dinuclear units are connected by glutartate ligands, forming one-dimensional double chains. These chains, are in turn bridged by 1,4-bis(pyridin-4-yl)butane ligands to form a two-dimensional layer structure parallel to (112). The carboxylate groups of the glutarate ligand bridge two copper(II) ions, forming a paddle-wheel-type Cu2(CO2)4 dinuclear secondary building unit. A crystallographic inversion centre is located midway between two CuII ions, with a Cu...Cu distance of 2.639 (3) Å. The coordination geometry of the unique CuII ion is slightly disorted square pyramidal, formed by four equatorial carboxylate O atoms and an axial pyridyl N atom.

Keywords

• crystal structure
• Cu–MOF
• glutarate
• 1,4-bis(pyridin-4-yl)butane