Atmospheric Chemistry and Physics (Oct 2023)
High enrichment of heavy metals in fine particulate matter through dust aerosol generation
- Q. Gao,
- Q. Gao,
- S. Zhu,
- K. Zhou,
- K. Zhou,
- J. Zhai,
- S. Chen,
- S. Chen,
- Q. Wang,
- Q. Wang,
- S. Wang,
- J. Han,
- J. Han,
- X. Lu,
- X. Lu,
- H. Chen,
- L. Zhang,
- L. Zhang,
- L. Wang,
- L. Wang,
- Z. Wang,
- Z. Wang,
- X. Yang,
- Q. Ying,
- H. Zhang,
- J. Chen,
- J. Chen,
- X. Wang,
- X. Wang
Affiliations
- Q. Gao
- Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China
- Q. Gao
- Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, China
- S. Zhu
- Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China
- K. Zhou
- Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China
- K. Zhou
- Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, China
- J. Zhai
- School of Environmental Science and Engineering, Southern University of Science and Technology, Shenzhen 518055, China
- S. Chen
- Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China
- S. Chen
- Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, China
- Q. Wang
- Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China
- Q. Wang
- Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, China
- S. Wang
- Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China
- J. Han
- Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China
- J. Han
- Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, China
- X. Lu
- Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China
- X. Lu
- Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, China
- H. Chen
- Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China
- L. Zhang
- Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China
- L. Zhang
- Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, China
- L. Wang
- Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China
- L. Wang
- Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, China
- Z. Wang
- Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China
- Z. Wang
- Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, China
- X. Yang
- School of Environmental Science and Engineering, Southern University of Science and Technology, Shenzhen 518055, China
- Q. Ying
- Zachry Department of Civil Engineering, Texas A&M University, College Station, TX 77843, USA
- H. Zhang
- Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China
- J. Chen
- Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China
- J. Chen
- Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, China
- X. Wang
- Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention, Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China
- X. Wang
- Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, China
- DOI
- https://doi.org/10.5194/acp-23-13049-2023
- Journal volume & issue
-
Vol. 23
pp. 13049 – 13060
Abstract
Dust is a major source of atmospheric aerosols. Its chemical composition is often assumed to be similar to the parent soil. However, this assumption has not been rigorously verified. Here, we generated dust aerosols from soils to determine if there is particle-size-dependent selectivity of heavy metals in the dust generation. Mn, Cd, Pb and other heavy metals were found to be highly enriched in fine-dust (PM2.5) aerosols, which can be up to ∼ 6.5-fold. To calculate the contributions of dust to atmospheric heavy metals, regional air quality models usually use the dust chemical profiles from the U.S. Environmental Protection Agency's (EPA) SPECIATE database, which does not capture the correct size-dependent selectivity of heavy metals in dust aerosols. Our air quality modeling for China demonstrates that the calculated contribution of fine-dust aerosols to atmospheric heavy metals, as well as their cancer risks, could have significant errors without using proper dust profiles.
