Hydrogen spillover assisted by oxygenate molecules over nonreducible oxides

Mingwu Tan; Yanling Yang; Ying Yang; Jiali Chen; Zhaoxia Zhang; Gang Fu; Jingdong Lin; Shaolong Wan; Shuai Wang; Yong Wang

doi:10.1038/s41467-022-29045-6

Nature Communications (Mar 2022)

Hydrogen spillover assisted by oxygenate molecules over nonreducible oxides

Mingwu Tan,
Yanling Yang,
Ying Yang,
Jiali Chen,
Zhaoxia Zhang,
Gang Fu,
Jingdong Lin,
Shaolong Wan,
Shuai Wang,
Yong Wang

Affiliations

Mingwu Tan: State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, and College of Chemistry and Chemical Engineering, Xiamen University
Yanling Yang: State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, and College of Chemistry and Chemical Engineering, Xiamen University
Ying Yang: State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, and College of Chemistry and Chemical Engineering, Xiamen University
Jiali Chen: State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, and College of Chemistry and Chemical Engineering, Xiamen University
Zhaoxia Zhang: State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, and College of Chemistry and Chemical Engineering, Xiamen University
Gang Fu: State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, and College of Chemistry and Chemical Engineering, Xiamen University
Jingdong Lin: State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, and College of Chemistry and Chemical Engineering, Xiamen University
Shaolong Wan: State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, and College of Chemistry and Chemical Engineering, Xiamen University
Shuai Wang: State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters, and College of Chemistry and Chemical Engineering, Xiamen University
Yong Wang: Voiland School of Chemical Engineering and Bioengineering, Washington State University

DOI: https://doi.org/10.1038/s41467-022-29045-6
Journal volume & issue: Vol. 13, no. 1
pp. 1 – 8

Abstract

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Spontaneous migration of H-atoms from metal particles to a nonreducible oxide support is generally limited by thermodynamics. Here, small oxygenate molecules are found to act as effective H-carriers to promote this process and lead to much improved hydrodeoxygenation rates on Pt-Fe/SiO2 catalysts.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

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