Nature Communications (Mar 2017)
Synthesis and reactivity of a mononuclear non-haem cobalt(IV)-oxo complex
- Bin Wang,
- Yong-Min Lee,
- Woon-Young Tcho,
- Samat Tussupbayev,
- Seoung-Tae Kim,
- Yujeong Kim,
- Mi Sook Seo,
- Kyung-Bin Cho,
- Yavuz Dede,
- Brenna C. Keegan,
- Takashi Ogura,
- Sun Hee Kim,
- Takehiro Ohta,
- Mu-Hyun Baik,
- Kallol Ray,
- Jason Shearer,
- Wonwoo Nam
Affiliations
- Bin Wang
- Department of Chemistry and Nano Science, Center for Biomimetic Systems, Ewha Womans University
- Yong-Min Lee
- Department of Chemistry and Nano Science, Center for Biomimetic Systems, Ewha Womans University
- Woon-Young Tcho
- Department of Chemistry and Nano Science, Center for Biomimetic Systems, Ewha Womans University
- Samat Tussupbayev
- Center for Catalytic Hydrocarbon Functionalizations, Institute for Basic Science (IBS)
- Seoung-Tae Kim
- Center for Catalytic Hydrocarbon Functionalizations, Institute for Basic Science (IBS)
- Yujeong Kim
- Western Seoul Center, Korea Basic Science Institute
- Mi Sook Seo
- Department of Chemistry and Nano Science, Center for Biomimetic Systems, Ewha Womans University
- Kyung-Bin Cho
- Department of Chemistry and Nano Science, Center for Biomimetic Systems, Ewha Womans University
- Yavuz Dede
- Department of Chemistry, Faculty of Science, Gazi University
- Brenna C. Keegan
- Department of Chemistry, University of Nevada
- Takashi Ogura
- Picobiology Institute, Graduate School of Life Science, University of Hyogo, RSC-UH LP Center
- Sun Hee Kim
- Western Seoul Center, Korea Basic Science Institute
- Takehiro Ohta
- Picobiology Institute, Graduate School of Life Science, University of Hyogo, RSC-UH LP Center
- Mu-Hyun Baik
- Center for Catalytic Hydrocarbon Functionalizations, Institute for Basic Science (IBS)
- Kallol Ray
- Department of Chemistry, Humboldt-Universität zu Berlin, Brook Taylor Strasse 2
- Jason Shearer
- Department of Chemistry, University of Nevada
- Wonwoo Nam
- Department of Chemistry and Nano Science, Center for Biomimetic Systems, Ewha Womans University
- DOI
- https://doi.org/10.1038/ncomms14839
- Journal volume & issue
-
Vol. 8,
no. 1
pp. 1 – 10
Abstract
Terminal CoIV-oxo species are key intermediates in various cobalt-mediated oxidation reactions, but little is known about their chemical properties. Here the authors generate and isolate a mononuclear non-haem CoIV-O complex and analyse its structure and reactivity towards a range of catalytic transformations.
