Acta Crystallographica Section E (Oct 2009)

Bis(3-acetyl-6-methyl-2-oxo-2H-pyran-4-olato)bis(dimethyl sulfoxide)nickel(II)

  • Amel Djedouani,
  • Sihem Boufas,
  • Abderrahmen Bendaas,
  • Magali Allain,
  • Gilles Bouet

DOI
https://doi.org/10.1107/S1600536809034655
Journal volume & issue
Vol. 65, no. 10
pp. m1205 – m1206

Abstract

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In the title compound, [Ni(C8H7O4)2{(CH3)2SO}2], the NiII atom is located on a crystallographic centre of symmetry and has a distorted octahedral coordination geometry of type MO6. The bidentate dehydroacetic acid (DHA) ligands occupy the equatorial plane of the complex in a trans configuration, and the dimethyl sulfoxide (DMSO) ligands are weakly coordinated through their O atoms in the axial positions.