Nature Communications (Oct 2020)

Dimer rattling mode induced low thermal conductivity in an excellent acoustic conductor

  • Ji Qi,
  • Baojuan Dong,
  • Zhe Zhang,
  • Zhao Zhang,
  • Yanna Chen,
  • Qiang Zhang,
  • Sergey Danilkin,
  • Xi Chen,
  • Jiaming He,
  • Liangwei Fu,
  • Xiaoming Jiang,
  • Guozhi Chai,
  • Satoshi Hiroi,
  • Koji Ohara,
  • Zongteng Zhang,
  • Weijun Ren,
  • Teng Yang,
  • Jianshi Zhou,
  • Sakata Osami,
  • Jiaqing He,
  • Dehong Yu,
  • Bing Li,
  • Zhidong Zhang

DOI
https://doi.org/10.1038/s41467-020-19044-w
Journal volume & issue
Vol. 11, no. 1
pp. 1 – 8

Abstract

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CuP2 has a puzzling thermal transport behavior, with low thermal conductivity but quite large mean sound speeds. Here, the authors conduct a systematical study of the atomic structure and lattice dynamics of CuP2 to reveal the origin, finding a dimer rattling behavior.