C.I. Basic Red 46 Removal from Sewage by Carbon and Silica Based Composite: Equilibrium, Kinetic and Electrokinetic Studies

Abstract

The worldwide production of colored products and intermediates is increasing year on year. The consequence of this is an increase in the number of liquid effluents containing toxic dyes entering the aquatic environment. Therefore, it is extremely important to dispose of them. One of the techniques for the elimination of environmentally harmful dyes is adsorption. The main purpose of this study was to explore the possibility of using a carbon and silica (C/SiO2)-based composite for the removal of the azo dye C.I. Basic Red 46 (BR46). The adsorption capacity of C/SiO2 was found to be temperature dependent and increased from 41.90 mg/g to 176.10 mg/g with a temperature rise from 293 K to 333 K in accordance with the endothermic process. The Langmuir isotherm model seems to be the better one for the description of experimental data rather than Freundlich or Dubinin–Radushkevich. The free energy (ΔGo) confirmed the spontaneous nature of BR46 adsorption by C/SiO2. Kinetic parameters revealed that BR46 uptake followed the pseudo-second-order equation; however, the external diffusion plays a significant role. Surfactants of cationic, anionic and non-ionic type influenced BR46 retention by C/SiO2. The electrokinetic results (solid surface charge density and zeta potential) indicated that the adsorption of cationic dye and surfactant influences the structure of the electrical double layer formed at the solid–liquid interface.

Keywords

• basic dye removal
• adsorption
• composite
• textile wastewaters
• zeta potential
• dye–surfactant complexes