Acta Crystallographica Section E (Oct 2010)

Bis(2,2′-bipyridine)(2-hydroxy-2,2-diphenylacetato)copper(II) nitrate dihydrate

  • Xuan Xu,
  • Shao-Wei Mai,
  • Chun Zheng,
  • Xiao-Jun Wang,
  • Yi-Fan Luo

DOI
https://doi.org/10.1107/S1600536810035555
Journal volume & issue
Vol. 66, no. 10
pp. m1245 – m1245

Abstract

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In the title complex, [Cu(C14H11O3)(C10H8N2)2]NO3·2H2O, the CuII atom is coordinated by four N atoms from two 2,2′-bipyridine ligands and two O atoms from one benzilate ligand in a distorted octahedral geometry. A supramolecular network is formed via intermolecular O—H...O and C—H...O hydrogen-bonding interactions. π–π stacking interactions between neighboring pyridine rings are also present, the centroid—centroid distance being 3.808 (2) Å.