Investigation of spatial and temporal variability in lower tropospheric ozone from RAL Space UV–Vis satellite products

Abstract

Ozone is a potent air pollutant in the lower troposphere and an important short-lived climate forcer (SLCF) in the upper troposphere. Studies using satellite data to investigate spatiotemporal variability of troposphere ozone (TO3) have predominantly focussed on the tropospheric column metric. This is the first study to investigate long-term spatiotemporal variability in lower tropospheric column ozone (LTCO3, surface–450 hPa sub-column) by merging multiple European Space Agency–Climate Change Initiative (ESA-CCI) products produced by the Rutherford Appleton Laboratory (RAL) Space. We find that in the LTCO3, the degree of freedom of signal (DOFS) from these products varies with latitude range and season and is up to 0.8, indicating that the retrievals contain useful information on lower TO3. The spatial and seasonal variation of the RAL Space products are in good agreement with each other, but there are systematic offsets of up to 3.0–5.0 DU between them. Comparison with ozonesondes shows that the Global Ozone Monitoring Experiment (GOME-1, 1996–2003), the SCanning Imaging Absorption spectroMeter for Atmospheric CartograpHY (SCIAMACHY, 2003–2010) and the Ozone Monitoring Instrument (OMI, 2005–2017) have stable LTCO3 records over their respective periods, which can be merged together. However, GOME-2 (2008–2018) shows substantial drift in its bias with respect to ozonesondes. We have therefore constructed a robust merged data set of LTCO3 from GOME-1, SCIAMACHY and OMI between 1996 and 2017. Comparing the LTCO3 differences between the 1996–2000 and 2013–2017 5-year averages, we find sizeable positive increases (3.0–5.0 DU) in the tropics/sub-tropics, while in the northern mid-latitudes, we find small-scale differences in LTCO3. Therefore, we conclude that there has been a substantial increase in tropical/sub-tropical LTCO3 during the satellite era, which is consistent with tropospheric column ozone (TCO3) records from overlapping time periods (e.g. 2005–2016).