Synergistic photoredox and copper catalysis by diode-like coordination polymer with twisted and polar copper–dye conjugation

Abstract

Synergistic photoredox–copper catalysis is limited by fluorescence quenching of Cu(II) ions to photoreductive dyes in solution. Here, the authors compromise photoreduction and Cu(II) catalysis by diode-like coordination polymer with twisted Cu(II)–dye conjugation, revealing its vast application vistas.