Materials Research (Jul 2018)

Conductive Composites Based on Polyurethane and Nanostructured Conductive Filler of Montmorillonite/Polypyrrole for Electromagnetic Shielding Applications

  • Patricia Cristine Vargas,
  • Claudia Merlini,
  • Sílvia Daniela Araújo da Silva Ramôa,
  • Rafael Arenhart,
  • Guilherme Mariz de Oliveira Barra,
  • Bluma Guenther Soares

DOI
https://doi.org/10.1590/1980-5373-mr-2018-0014
Journal volume & issue
Vol. 21, no. 5

Abstract

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In this study, composites based on polyurethane (PU) derived from castor oil and montmorillonite/polypyrrole doped with dodecylbenzenesulfonic acid (MMt-PPy.DBSA) were developed. In order to investigate the potential use of these materials for electromagnetic shielding applications, the electrical and mechanical properties of PU/MMt-PPy.DBSA composites were determined and compared with composites containing neat PPy.DBSA. The electrical conductivity of PU/MMt-PPy.DBSA composites was found to be higher than those for PU/PPy.DBSA with a similar filler content. Additionally, with a higher conductive additive content, significant increases in the tensile stress (σ) and elastic modulus (E) were observed, suggesting that MMt-PPy.DBSA acts as reinforcing agent for the PU matrix. The electromagnetic interference shielding effectiveness (EMI SE) of composites is mainly dependent on the morphology and filler content. The PU/MMt-PPy.DBSA composite containing 25 wt % of MMt-PPy.DBSA showed a maximum EMI SE of -21 dB, which is similar to the value required for commercial applications (-20 dB). The results revealed that PU/MMt-PPy.DBSA composites are promising materials for electromagnetic shielding applications.

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