Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry (Jun 2016)

STRUCTURE AND SOME BIOLOGICAL PROPERTIES OF Fe(III) COMPLEXES WITH NITROGEN-CONTAINING LIGANDS

  • Ion Bulhac,
  • Alexandra Deseatnic-Ciloci,
  • Paulina Bourosh,
  • Janetta Tiurina,
  • Olga Bologa,
  • Cezara Bivol,
  • Steliana Clapco,
  • Ana Verejan,
  • Svetlana Labliuc,
  • Olga Danilescu

Abstract

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Four coordination compounds of iron(III) with ligands based on hydrazine and sulfadiazine: FeCl3·digsemi·2H2O (I) (digsemi-semicarbazide diacetic acid dihydrazide, [Fe(HL)SO4] (II) (НL - sulfadiazine), [Fe(H2L1)(H2O)2](NO3)3·5H2O (III) (H2L1-2,6-diacetylpyridine bis(nicotinoylhydrazone) and [Fe(H2L2)(H2O)2](NO3)3•1.5H2O (IV) (H2L2 - 2,6-diacetylpyridine bis(isonicotinoylhydrazone) were synthesized. The spectroscopic and structural characterisation as well as their biological, properties are presented.

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