Design of ionic liquids as liquid desiccant for an air conditioning system

Abstract

Suitable control of the humidity can contribute to electric energy savings. However, the present dehumidification system has many weak points. The liquid desiccant air-conditioning system has recently gained growing interest from the stand point of reducing energy consumption during dehumidification. In order to find the appropriate ionic liquids (ILs) as a desiccant for the liquid desiccant air-conditioner system, we conducted a systematic evaluation of the humidification capability of 16 types of ILs. Among the tested ILs, tributyl(methyl)phosphonium dimethyl phosphate ([P4441][DMPO4]) exhibited the best dehumidification capacity and had a less corrosive effect on four types of metals as possible piping materials. It should be noted that this [P4441][DMPO4] has a very stable nature and produced no odor while conducting the experiment and storing for over 1 year at room temperature under ambient conditions. Furthermore, it was revealed that a 77% (w/w) aqueous solution of [P4441][DMPO4] worked as an efficient desiccant liquid for the liquid desiccant air-conditioner system. Keywords: Dehumidification, Liquid desiccant, Ionic liquids, Air-conditioner system, Phosphonium ILs