Development of LaxCa1-xMnO3 materials for Bezaktiv Blue removal in aqueous media

Abstract

In this work, mixed oxides of LaxCa1-xMnO3 perovskite type (x = 0, 0.5 and 1.0) were synthesized through modified proteic method using collagen and calcination process at 700 °C/2 h in order to remove the commercial textile dye Bezaktiv Blue S-MAX from water. Oxides were characterized using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), N2 physisorption, scanning electron microscopy (SEM) and point of zero charge (PZC) techniques while the dye only by the first two techniques. The XRD showed that perovskite monophase was obtained for x = 0.5 and 1.0. However, for x = 0, the low crystalline perovskite phase was obtained in the midst of precursor oxides. FTIR showed the adsorption process did not damage the adsorbents structure. The successful obtained materials have meso and macroporous with slit or cavity shape, rough surface and particles with varying sizes. The pseudo-second-order model was the one that best fit the kinetic data. The process must occur through electrostatic surface interactions between the adsorbent surface and the dye molecule. For the equilibrium study, Langmuir isotherm is the most suitable when using LaMnO3 adsorbent, while Freundlich isotherm was better suited when used the other two materials. The adsorbents were termally regenerated and reused five times. The best performance was exhibited by LaMnO3. HIGHLIGHTS Successful preparation of LaxCa1-xMnO3 (x = 0.5 and 1.0) materials using low cost method.; Effective removal of Bezaktiv Blue dye using LaxCa1-xMnO3.; The LaMnO3 maintained your adsorptive capacity throughout regeneration cycles.; The La0.5Ca0.5MnO3 became a catalyst after the second regeneration and the CaMnO3 had its structure consolidated throughout regeneration cycles.; The materials pores contributed to adsorption process.;

Keywords

• adsorption
• bezaktiv blue
• modified proteic method
• perovskite oxide
• regeneration
• reuse