Journal of Materiomics (Jan 2024)

Hybrid improper ferroelectricity and phase transition behavior of Li2Nd2Ti3O10 ceramics with A-site ordered triple-layer Ruddlesden-Popper structure

  • Bi Hui Zhang,
  • Diming Xu,
  • Rui Ze Guo,
  • Lu Liu,
  • Xiao Qiang Liu,
  • Xiang Ming Chen

Journal volume & issue
Vol. 10, no. 1
pp. 145 – 153

Abstract

Read online

Hybrid improper ferroelectricity has been extensively reported through theoretical prediction and experimental investigation in the oxides with Ruddlesden-Popper (R–P) structures. However, the experimentally reported ferroelectric materials based on triple-layer R–P structures are rare, and the weak ferroelectricity impedes its practical application. In the present work, the single-phase Li2Nd2Ti3O10 ceramics with A-site cation ordered triple-layer R–P structure was obtained by spark plasma sintering technique, and the crystal structure of P21ab symmetry was revealed by neutron powder diffraction and transmission electron microscope analysis. Furthermore, the switchable ferroelectricity in Li2Nd2Ti3O10 ceramics has been observed at room temperature, and the saturated polarization-electric field hysteresis loop was obtained with Pr = 0.4 μC/cm2 under the electric field of 250 kV/cm. The phase transition behavior of Li2Nd2Ti3O10 oxides was revealed by the temperature-dependence Raman and dielectric spectra combined with the piezoelectric property.

Keywords