Molten salt corrosion behavior of laser remelted PS-PVD YSZ thermal barrier coatings

Abstract

Molten salt from the service environment leaches Y2O3 from yttria-stabilized zirconia (YSZ), threatening the security of thermal barrier coatings (TBCs). In this study, we compared the molten salt corrosion resistances of YSZ coatings prepared via plasma-spraying physical vapor deposition (PS-PVD) before and after laser remelting. At 1000 °C, the molten salt reacted with YSZ particulates in the PS-PVD YSZ coating and infiltrated the gaps between quasi-columnar crystals, resulting in phase transition of the coating and column breakage. A dense glazed layer was formed on the YSZ coating surface after remelting by the low-energy-density laser, which prohibited the penetration of molten salt and improved the hot corrosion resistance of the YSZ coating. By contrast, the failure of the high-energy-density laser-treated YSZ coating was accelerated due to the significant interfacial stress from the thick glazed layer and volume expansion caused by the corrosion products. Our investigation revealed the structural evolution of the PS-PVD YSZ coating under hot corrosion conditions, emphasized the role of laser remelting, and could serve as a guideline for TBCs modification.

Keywords

• Yttria-stabilized zirconia (YSZ) coating
• Plasma spraying physical vapor deposition (PS-PVD)
• Laser remelting
• Molten salt corrosion