Synthesis, structural study and electrochemical properties of copper(II) complexes derived from benzene- and p-toluenesulphonylhydrazone

Abstract

The synthesis and characterization of benzene- and p-toluenesulphonylhydrazones derived from salicylaldehyde and 2-hydroxy-1-naphthaldehyde and their Cu(II) complexes are reported. The compounds were characterized on the basis of elemental analyses, electronic and IR spectra, magnetic moments, and conductance measurements. The electrochemical behavior of the Cu(II) complexes was investigated in DMSO by cyclic voltammetry (CV), rotating disc electrode (RDE) and coulometry. The oxidative polymerization of the copper complexes on a glassy carbon electrode was carried out in DMSO.

Keywords

• sulphonylhydrazone-cu(ii) complex
• cyclic voltammetry