Feasibility Study of the Paper Sludge Properties in Manufacturing Recycled Filler

Abstract

The mineralization of inorganic components in paper sludge offers potential for their re-use in various fields. This study synthesized carbonates based on the minerals present in paper sludge and aimed to investigate the control of particle size distribution and particle shape of the synthesized carbonates. First, the physicochemical and thermal properties of paper mill sludge and ash were evaluated using a spectrophotometer, XRF, and TGA. Paper sludge ash was obtained by incinerating the paper sludge, followed by a carbonation reaction using CO2 gas injection and pH neutralization to produce recycled fillers. The average particle size, crystal lattice structure, and morphology of the recycled fillers were analyzed using a particle size analyzer, XRD, and FE-SEM. The results indicate that the recycled filler produced from coating paper sludge exhibited similar brightness and morphology to conventional paper-based fillers, suggesting its potential to replace commercial PCC (Precipitated Calcium Carbonate). In contrast, the recycled filler manufactured using old corrugated container mill sludge was deemed unsuitable due to its low hydration activity.

Keywords

• paper sludge
• waste management
• recycling
• filler