High Photocatalytic Activity under Visible Light for a New Morphology of Bi₂WO₆ Microcrystals

Abstract

In this work, a new morphology was obtained for bismuth tungstate (Bi2WO6-glyc) using a hydrothermal method with the addition of glycerol as a surfactant. In order to compare, the bismuth tungstate without glycerol as the surfactant, i.e., Bi2WO6, was synthesized. Structural characterization by XRD and Rietveld refinement confirmed the orthorhombic structure as a single phase for all samples with high crystallinity. All active modes in Raman spectroscopy for the orthorhombic phase of bismuth tungstate were confirmed in agreement with XRD analysis. N2 adsorption/desorption and size pore distribution confirmed the high surface area (85.7 m2/g) for Bi2WO6-glyc when compared with Bi2WO6 (8.5 m2/g). The optical band gap by diffuse reflectance was 2.78 eV and 2.88 eV for Bi2WO6-glyc and Bi2WO6, respectively. SEM images confirmed the different morphology for these materials, and microstructures with cheese crisp were observed for Bi2WO6-glyc (cheese crisp). On the other hand, flower-like microcrystals were confirmed for Bi2WO6 sample. The photocatalytic performance of Bi2WO6-glyc (94.2%) in the photodegradation of rhodamine B (RhB) dye solutions at 60 min was more expressive than Bi2WO6 (81.3%) and photolysis (8.2%) at 90 min.

Keywords

• glycerol
• Bi₂WO₆
• photocatalysis
• organic dye