THE REASONS OF KINETIC AND STRUCTURAL FEATURES OF METHYL METHACRYLATE POLYMERIZATION, INITIATED BY COBALT (II) METHACRYLOYLACETONATE

Abstract

The reasons of kinetic and structural features of methyl methacrylate polymerization, initiated by cobalt (II) 5- methyl-5-hexene-2,4-dionate are considered. It is shown that abnormally low rates of polymerization and the formation of cross-linked polymers are connected with the formation of conjugated metal chelate radicals and with the polar factor of monomer.

Keywords

• вініл-b-дикетонати
• радикальна полімеризація
• поліметилметакрилат
• структурування