Recent Progress on Improving Low-Temperature Activity of Vanadia-Based Catalysts for the Selective Catalytic Reduction of NO<i>_x</i> with Ammonia

Abstract

Selective catalytic reduction of NOx with NH3 (NH3-SCR) has been successfully applied to abate NOx from diesel engines and coal-fired industries on a large scale. Although V2O5-WO3(MoO3)/TiO2 catalysts have been utilized in commercial applications, novel vanadia-based catalysts have been recently developed to meet the increasing requirements for low-temperature catalytic activity. In this article, recent progress on the improvement of the low-temperature activity of vanadia-based catalysts is reviewed, including modification with metal oxides and nonmetal elements and the use of novel supports, different synthesis methods, metal vanadates and specific structures. Investigation of the NH3-SCR reaction mechanism, especially at low temperatures, is also emphasized. Finally, for low-temperature NH3-SCR, some suggestions are given regarding the opportunities and challenges of vanadia-based catalysts in future research.

Keywords

• selective catalytic reduction
• vanadia-based catalysts
• low-temperature activity
• reaction mechanism