Synthesis of Metal-Organic Framework (MOF) Cr-PTC-HIna for Heavy Metal Ion Adsorption

Nurhasni Nurhasni; Adawiah Adawiah; Wahyudin Wahyudin; Rizka Hadriyani; Leni Andriyani; Rizkha Fadhilla; Agustino Zulys; Dede Sukandar

doi:10.9767/bcrec.20069

Bulletin of Chemical Reaction Engineering & Catalysis (Apr 2024)

Synthesis of Metal-Organic Framework (MOF) Cr-PTC-HIna for Heavy Metal Ion Adsorption

Nurhasni Nurhasni,
Adawiah Adawiah,
Wahyudin Wahyudin,
Rizka Hadriyani,
Leni Andriyani,
Rizkha Fadhilla,
Agustino Zulys,
Dede Sukandar

Affiliations

Nurhasni Nurhasni: Department of Chemistry, Faculty of Science and Technology, UIN Syarif Hidayatullah Jakarta, Jl. Ir. H. Juanda No. 95 Ciputat Tangerang Selatan 15412, Indonesia
Adawiah Adawiah: ORCiD; Integrated Laboratory Centre, Faculty of Science and Technology UIN Syarif Hidayatullah Jakarta, Indonesia
Wahyudin Wahyudin: Research Center for Advanced Materials, National Research and Innovation Agency, KST BJ Habibie, South Tangerang 15314, Jl. Ir. H. Juanda No. 95 Ciputat Tangerang Selatan 15412, Indonesia
Rizka Hadriyani: Department of Chemistry, Faculty of Science and Technology, UIN Syarif Hidayatullah Jakarta, Jl. Ir. H. Juanda No. 95 Ciputat Tangerang Selatan 15412, Indonesia
Leni Andriyani: Department of Chemistry, Faculty of Science and Technology, UIN Syarif Hidayatullah Jakarta, Jl. Ir. H. Juanda No. 95 Ciputat Tangerang Selatan 15412, Indonesia
Rizkha Fadhilla: Department of Chemistry, Faculty of Science and Technology, UIN Syarif Hidayatullah Jakarta, Jl. Ir. H. Juanda No. 95 Ciputat Tangerang Selatan 15412, Indonesia
Agustino Zulys: ORCiD; Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Indonesia, Jl. Lingkar Kampus Raya, Pondok Cina, Beji, Depok, Jawa Barat 16424, Indonesia
Dede Sukandar: Department of Chemistry, Faculty of Science and Technology, UIN Syarif Hidayatullah Jakarta, Jl. Ir. H. Juanda No. 95 Ciputat Tangerang Selatan 15412, Indonesia

DOI: https://doi.org/10.9767/bcrec.20069
Journal volume & issue: Vol. 19, no. 1
pp. 86 – 98

Abstract

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As an adsorbent material, Metal-Organic Framework (MOF) provides several advantages, such as large surface area and pore volume, as well as stability in aqueous systems both in acidic, basic, and neutral conditions. The research successfully made a metal organic framework (MOF) from chromium and perylene that was modulated by isonicotinic acid. This was done using three different methods: hydrothermal (Cr-PTC-HIna-HT), solvothermal (Cr-PTC-HIna-ST), and sonochemical (Cr-PTC-HIna-SC). The Cr-PTC-HIna-SC showed the greatest Pb2+ ion adsorption capacity. The optimum adsorption of Pb2+ ions occurred at 150 ppm Pb2+ ion concentration, pH 5, 90 minutes of contact time, and an adsorption capacity of 149.95 mg/g at 35 °C. The dominant adsorption isotherm model is the Langmuir isotherm model with R2 = 0.9867 and follows the pseudo-second-order. The selectivity test showed that Cr-PTC-HIna-SC MOF could adsorb more Cd2+ ions than Pb2+ ions, with 250 mg/g being the best amount.

Published in Bulletin of Chemical Reaction Engineering & Catalysis

ISSN: 1978-2993 (Online)
Publisher: Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
Country of publisher: Indonesia
LCC subjects: Technology: Chemical technology: Chemical engineering
Website: https://journal.bcrec.id/index.php/bcrec

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