Acta Crystallographica Section E (Nov 2013)

Tris[4-bromo-2-(methyliminomethyl)phenolato-κ2N,O]cobalt(III)

  • Qiu-Ping Huang,
  • Chun-Lian Zhang,
  • Ru-Xia Zhao,
  • Li Yang,
  • Xi-Fu Jiang

DOI
https://doi.org/10.1107/S1600536813027591
Journal volume & issue
Vol. 69, no. 11
pp. m601 – m601

Abstract

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In the title compound, [Co(C8H7BrNO)3], the CoIII ion is coordinated in a slightly distorted octahedral environment by three N atoms and three O atoms from three bidentate 4-bromo-2-(methyliminomethyl)phenolate ligands. The dihedral angles between the benzene rings are 82.6 (2), 57.1 (2) and 62.9 (2)°. In the crystal, molecules are linked by pairs of weak C—H...Br hydrogen bonds, forming inversion dimers.